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Enantioselective synthesis of valoneic acid derivative |
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| Authors: | Hitoshi Abe Yusuke Sahara Yasuo Takeuchi |
| Affiliation: | a Graduate School of Medicine, Dentistry, and Pharmaceutical Sciences, Okayama University, Okayama 700-8530, Japan b Advanced Science Research Center, Okayama University, Okayama 700-8530, Japan c Faculty of Pharmaceutical Sciences at Kagawa Campus, Tokushima Bunri University, Sanuki, Kagawa 769-2193, Japan |
| Abstract: | The enantioselective synthesis of trimethyl octa-O-methylvaloneate (1) was accomplished using the Bringmann’s ‘lactone concept’, which involves the intramolecular biaryl coupling reaction of a phenyl benzoate derivative and the asymmetric lactone-opening reaction. |
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