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Structural and optical properties of Bi3.25Nd0.75Ti3O12 ferroelectric thin films
Authors:JH Ma  XJ Meng  JL Sun  JQ Xue  ZG Hu  FW Shi  T Lin  JH Chu
Institution:(1) National Laboratory for Infrared Physics, Shanghai Institute of Technical Physics, Chinese Academy of Sciences, 500 Yu Tian Road, Shanghai, 200083, P.R. China
Abstract:Ferroelectric Bi3.25Nd0.75Ti3O12 (BNT) thin films were grown on (111)Pt/Ti/SiO2/Si substrates by a chemical solution method. The films were composed of large rod-like grains. XRD and Raman spectroscopy measurements showed they were polycrystalline perovskite structure with a good crystallinity. Pt/BNT/Pt capacitors had been fabricated and showed good ferroelectricity. The optical constants (n, k) of BNT thin films in the wavelength ranges of 0.2–1.7 μm and 2.5–11.4 μm were obtained by spectroscopic ellipsometry measurements. The dispersion of the refractive index in the interband transition region followed the single electronic oscillator model. The optical band gap was found to be about 3.61 eV. PACS 77.84.-s; 78.20.Ci; 77.80.-e
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