| 八种腐植酸热重分析及其热分解动力学的研究 |
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| 引用本文： | 余守志 朱琰. 八种腐植酸热重分析及其热分解动力学的研究[J]. 燃料化学学报, 1990, 18(1): 8-15 |
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| 作者姓名： | 余守志 朱琰 |
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| 作者单位： | 河南省科学院化学研究所 郑州(余守志，朱琰)，河南省科学院化学研究所 郑州(陈荣峰) |
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| 摘 要： |
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| 关 键 词： | 腐植酸 热重分析 热分解 活化能 |
THERNIOGRAVIMETRIC ANALYSIS OF EIGHT HUMIC ACIDS AND STUDY ON HEAT-DEGRADATION KINETICS |
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| Yu Shouzhi Zhu Yan Chen Rongfeng. THERNIOGRAVIMETRIC ANALYSIS OF EIGHT HUMIC ACIDS AND STUDY ON HEAT-DEGRADATION KINETICS[J]. Journal of Fuel Chemistry and Technology, 1990, 18(1): 8-15 |
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| Authors: | Yu Shouzhi Zhu Yan Chen Rongfeng |
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| Abstract: | the TG and DTG curves of eight humic acids from different origin were determined and the peaks of those curves were classified. The kinetic parameters for heat-degradation of eight HA were obtained by Coast-Redfern method, the activation energy of five humic acids from weathered coal at decarboxyl stage is smaller, from 58.6 to 86.46 kJ/mol; that of HA from peat is higher from 84.8 to 112.20 kJ/mol; while that of HA from soil is the highest, equals to 156.33 kJ/mol, which agrees with those in the literature.This paper first reported the kinetic equations and parameters for eight humic acids at the stage of multi-ring hydrocarbons and various aromatic nucleus heat-degradation. |
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| Keywords: | humic acid kinetics of heat-degradation activation energy |
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