| 熔盐快速合成Pb1-xLaxTiO3粉体 |
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| 引用本文： | 蔡宗英,邢献然,邓金侠,于然波,刘桂荣.熔盐快速合成Pb1-xLaxTiO3粉体[J].无机化学学报,2006,22(8):1421-1425. |
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| 作者姓名： | 蔡宗英 邢献然 邓金侠 于然波 刘桂荣 |
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| 作者单位： | 1. 北京科技大学理化系,北京,100083;军械工程学院,石家庄,050003
2. 北京科技大学理化系,北京,100083 |
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| 基金项目： | 国家高技术研究发展计划(863计划);教育部人才基金TRAPOYT资助项目 |
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| 摘 要： | 采用全氧化物为原料，利用熔盐法合成了Pb1-xLaxTiO3(0.0≤x≤0.40)，当x=0.45时，烧绿石相La2Ti2O7出现。计算了合成反应活化能，并在700 ℃下在NaCl-KCl体系中仅用5 min就合成了Pb0.9La0.1TiO3。Pb1-xLaxTiO3陶瓷在0.00≤x<0.25时，晶体结构为四方相，在0.25≤x≤0.40时为立方相。采用700 ℃ NaCl-KCl和900 ℃的Na2SO4-K2SO4两种熔盐体系获得了尺寸分布集中的球形颗粒，这些表明熔盐法晶体生长为扩散控制生长机理。
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| 关 键 词： | 熔盐合成(MSS) PLT 陶瓷粉末 |
| 文章编号： | 1001-4861（2006）08-1421-05 |
| 收稿时间： | 2006-05-28 |
| 修稿时间： | 2006-06-21 |
Rapid Synthesis of Pb1-xLaxTiO3 Powders in Molten Salt Flux |
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| CAI Zong-Ying,XING Xian-Ran,DENG Jin-Xi,YU Ran-Bo and LIU Gui-Rong.Rapid Synthesis of Pb1-xLaxTiO3 Powders in Molten Salt Flux[J].Chinese Journal of Inorganic Chemistry,2006,22(8):1421-1425. |
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| Authors: | CAI Zong-Ying XING Xian-Ran DENG Jin-Xi YU Ran-Bo and LIU Gui-Rong |
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| Institution: | Department of Physical Chemistry, University of Science & Technology Beijing, Beijing 100083;Institute of Ordnance Engineering, Shijiazhuang 050003,Department of Physical Chemistry, University of Science & Technology Beijing, Beijing 100083,Department of Physical Chemistry, University of Science & Technology Beijing, Beijing 100083,Department of Physical Chemistry, University of Science & Technology Beijing, Beijing 100083 and Department of Physical Chemistry, University of Science & Technology Beijing, Beijing 100083 |
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| Abstract: | Perovskite-type compounds Pb1-xLaxTiO3 in the composition range of x from 0 to 0.45 were synthesized using simple oxides from 700 ℃ to 1 000 ℃ by molten salt synthesis (MSS) and a small amount of La2Ti2O7 pyrochlore phase was detected in the XRD patterns for x=0.45. The activation energy for particle growth in MSS was calculated, and the Pb0.9La0.1TiO3 was synthesized at 700 ℃ for only 5 min. The perovskite phase for the material prepared was tetragonal for 0.0≤x ≤0.25 and cubic for 0.25 ≤x≤0.40. The average particle size was different for samples prepared in NaCl-KCl and Na2SO4-K2SO4 system, but the shape was all spherical for samples obtained from both systems. The same spherical shape could be explained by the diffusion control mechanism for the particle growth into spherical shapes. |
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| Keywords: | molten salt synthesis (MSS) PLT ceramic powder |
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