A decanuclear oxomolybdenum(V,VI) cluster with 4-isopropylpyridine |
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Authors: | Barbara Modec Jurij V. Brenčič Gerald Giester |
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Abstract: | The title centrosymmetric cluster octakis(4-isopropylpyridine-N)-di-μ4-oxo-hexa-μ3-oxo-octa-μ2-oxo-decaoxooctamolybdenum(V)dimolybdenum(VI), [Mo10O26(C8H11N)8], consists of ten Mo atoms connected together by bridging oxo groups. Pentavalent Mo atoms are linked into four Mo2V pairs by metal–metal single bonds with lengths of 2.5637 (6) and 2.6132 (6) Å. |
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