An Observation on the Microphase Separation of Poly(methyl methacrylate)-block-Polystyrene Copolymer |
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Authors: | Jie DENG Xin Song LI Zheng Mei WANG Gang SHAO Ju Zheng LIU |
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Affiliation: | Jie DENG,Xin Song LI*,Zheng Mei WANG,Gang SHAO,Ju Zheng LIU Department of Chemical Engineering,Southeast University,Nanjing 210096 |
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Abstract: | The phase behavior of a well-defined poly(methyl methacrylate)- b- polystyrene block copolymer was studied by transmission electron microscope. The results show that a microphase transition may have occurred in the copolymer film. A kind of lamellae and an ordered bicontinuous double-diamond morphology are observed clearly. The lamellar morphology reveals a larger period of about 400 nm. |
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Keywords: | Block copolymer phase separation atom transfer radical polymerization TEM. |
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