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An Observation on the Microphase Separation of Poly(methyl methacrylate)-block-Polystyrene Copolymer
Authors:Jie DENG  Xin Song LI  Zheng Mei WANG  Gang SHAO  Ju Zheng LIU
Affiliation:Jie DENG,Xin Song LI*,Zheng Mei WANG,Gang SHAO,Ju Zheng LIU Department of Chemical Engineering,Southeast University,Nanjing 210096
Abstract:The phase behavior of a well-defined poly(methyl methacrylate)- b- polystyrene block copolymer was studied by transmission electron microscope. The results show that a microphase transition may have occurred in the copolymer film. A kind of lamellae and an ordered bicontinuous double-diamond morphology are observed clearly. The lamellar morphology reveals a larger period of about 400 nm.
Keywords:Block copolymer   phase separation   atom transfer radical polymerization   TEM.
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