M(III)(bpym)(CN)(4)](-): a suitable building block to design ferrimagnetic cyano-bridged heterobimetallic chains (M = Fe, Cr; bpym = 2,2'-bypyrimidine) |
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| Authors: | Visinescu Diana Toma Luminita Marilena Lloret Francesc Fabelo Oscar Ruiz-Pérez Catalina Julve Miguel |
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| Institution: | Departament de Química Inorgànica/Instituto de Ciencia Molecular (ICMol), Facultat de Química de la Univeristat de València, Edificio de Institutos s/n, Paterna, 46980, València, Spain. miguel.julve@uv.es. |
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| Abstract: | Two cyano-bridged M(III)Mn(III) M = Fe () and Cr ()] ferrimagnetic chains are reported; exhibits metamagnetism with two critical fields of 1250 G and 2.0 T which correspond to the overcoming by the applied dc field of the inter- and intrachain magnetic interactions, respectively. |
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