Synthesis and Structural Characterization of Mono-and Di-nuclear Zinc( Ⅱ ) Coordination Compounds of Triphenylphosphoniopropionate |
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作者姓名: | Mak Thomas C. W. |
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作者单位: | Department of |
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基金项目: | SupportedbyagrantfromLiuHuiResearchCentreforAppliedMathematicsofNankaiUnivesityandTianjinUnversity(No.H10114). |
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摘 要: | IntroductionThe coordination chemistry of zinc(Ⅱ)has beensubjected to extensive study in the past decades owingto its importance in life science1].It has been foundthat zinc(Ⅱ)ions are crucially involved in the activesites of over300metalloenzymes and their role is notonly confined to catalysis and gene expression.Further-more,the presence of zinc(Ⅱ)helps to stabilize thetertiary and quaternary structures of proteins and nucle-ic acids2—4].Like cadmium(Ⅱ),zinc(Ⅱ)is clearly amongthose m…
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关 键 词: | 合成 晶体结构 三苯基磷基丙酸酯 锌配合物 单核配合物 双核配合物 四膦内铵盐 |
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