Ruthenium clusters containing the [2.2] paracyclophane ligand: Recent developments in arene-cluster chemistry |
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| Authors: | Paul J Dyson Brian F G Johnson Caroline M Martin |
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| Institution: | (1) Department of Chemistry, The University of Edinburgh, West Mains Road, EH9 3JJ Edinburgh, UK |
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| Abstract: | In this article we review the synthesis, reactivity, and characterization of a number of clusters bearing the 2.2] paracyclophane ligand with nuclearities ranging from two to eight. Particular attention is focused on the different coordination modes that paracyclophane adopts; these being µ1-
6, µ2-
3 :
3, µ3-
1 :
2 :
2, and µ3-
2 :
2 :
2. Structural modifications which take place within the ring system on bonding in these various modes are also discussed. |
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| Keywords: | Cluster paracyclophane carbonyl ruthenium |
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