Self-reinforcement of liquid-crystal polymers at static and dynamic loading

The self-reinforcement effect of a solid uniaxially oriented SVM-K liquid-crystal polyamide and a copolyester of hydroxybenzoic and hydroxynaphthoic acids has been investigated by tensile-strength, stress-relaxation, and dynamic methods. The samples were prepared by spinning from lyotropic solution (SVM-K) and from a thermotropic melt (polyester). The tensile-strength and stress-relaxation tests were performed on complex fibers and the dynamic test on single fibers. The set of stress-strain curves, changing from a convex shape with two linear sections (at room temperature) to a concave shape (at high temperatures) is shown for both materials in Fig. 1. There is a pronounced difference between the deformation mechanisms at low and high strains in the stability of rigidity. At high temperatures the rigidity becomes less than the initial one during deformation and the current modulus at high strains has the same value within large ranges of temperatures and strains (Fig. 2). A low-deformation transition of another physical parameter than the yield-stress has been found. The stress-strain diagram for both investigated polymers has been generalized by using the constant value of the current modulus for the normalization of the stress value (Fig. 3). The stress-relaxation phenomena are shown to be anomalous. At high temperatures the stress-relaxation intensity decreases with increasing deformation, i.e., after deformation the polymer is characterized by a stability of rigidity which is higher than the initial value (Fig. 4). The dynamic modulus appears to increase with increasing deformation rate (Fig. 5). Due to these peculiarities the liquid-crystal polymers must be considered not only as normal high-modulus reinforcements for composite materials but also as materials, self-reinforcing under loading.Translated from Mekhanika Kompozitnykh Materialov, Vol. 30, No. 4, pp. 435–441, July–August, 1994.