A ferrocene based palladacyclic precatalyst for the Suzuki cross-coupling of aryl chlorides |
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| Authors: | Roca Francesc X Richards Christopher J |
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| Affiliation: | Department of Chemistry, Queen Mary, University of London, Mile End Road, London, UK E1 4NS. |
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| Abstract: | ![]()
Addition of palladium acetate to 2-(dicyclohexylphosphino)-phenylferrocene gave palladacycle 16 that is a very effective precatalyst for the Suzuki cross-coupling of aryl chlorides at room temperature (1 mol% 16) or 60 degrees C (> or = 0.01 mol% 16). |
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