Supercritical fluid thermodynamics from equations of state |
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Authors: | Vincent Giovangigli Lionel Matuszewski |
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Institution: | a CMAP, CNRS, Ecole Polytechnique, 91128 Palaiseau cedex, Franceb ONERA, Centre de Palaiseau, 91198 Palaiseau cedex, France |
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Abstract: | Supercritical multicomponent fluid thermodynamics are often built from equations of state. We investigate mathematically such a construction of a Gibbsian thermodynamics compatible at low density with that of ideal gas mixtures starting from a pressure law. We further study the structure of chemical production rates obtained from nonequilibrium statistical thermodynamics. As a typical application, we consider the Soave-Redlich-Kwong cubic equation of state and investigate mathematically the corresponding thermodynamics. This thermodynamics is then used to study the stability of H2-O2-N2 mixtures at high pressure and low temperature as well as to illustrate the role of nonidealities in a transcritical H2-O2-N2 flame. |
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Keywords: | Thermodynamics Nonideal Supercritical Mathematical structure Kinetics Stability |
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