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To the problem of first order phase transition at the fluid–fluid interface |
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| Authors: | Ludmila Boinovich Alexandre Emelyanenko |
| Institution: | aA.N. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Leninsky prospect 31, 119991 Moscow, Russia |
| Abstract: | The thermodynamic analysis is developed to describe both the surface freezing and the surface melting in various systems. The key physico-chemical parameters determining the shift of the freezing temperature in boundary phases in comparison to the temperature of corresponding bulk phase transition are discussed. |
| Keywords: | Surface freezing Surface melting Phase transitions Boundary phases Surface forces |
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