| 配位负载金属卟啉的合成及催化氧化环已烷的性能研究 |
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| 引用本文： | 唐渝,王小白,桂明德,朱申杰.配位负载金属卟啉的合成及催化氧化环已烷的性能研究[J].化学研究与应用,1998(5). |
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| 作者姓名： | 唐渝 王小白 桂明德 朱申杰 |
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| 作者单位： | 暨南大学化学系，国立新加坡大学化学系，南开大学化学系 |
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| 基金项目： | 国家自然科学基金,国务院侨办基金 |
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| 摘 要： | 合成了三种与咪唑配体键合的新型载体，并通过其与四苯基卟啉铁和卟啉锰配位得到了改性的负载金属卟啉催化剂。讨论了它们在催化氧化环己烷反应中的稳定性、活性等，结果表明配位负载方式明显提高了金属卟啉的稳定性，其中硅胶配位负载锰卟啉还具有较高的活性。
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| 关 键 词： | 负载 配位 金属卟啉 催化氧化 |
STUDIES ON SYNTHESIS AND THEIR PROPERTIES IN CATALYTIC OXIDATION OF CYCLOHEXANE OF SUPPORTED METALLOPORPHYRINS BY COORDINATION |
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| Tang,Yu.STUDIES ON SYNTHESIS AND THEIR PROPERTIES IN CATALYTIC OXIDATION OF CYCLOHEXANE OF SUPPORTED METALLOPORPHYRINS BY COORDINATION[J].Chemical Research and Application,1998(5). |
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| Authors: | Tang Yu |
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| Abstract: | Three new supporters bonded with ligand imidazole have been prepared.Modified catalysts of metalloporphyrins have been obtained by coordination of TPPFeCl or TPPMnCl with supporters.Their stabilities and activities in catalytic oxidative reaction of cyclohexane were discussed.The results showed the way of coordinating suport had improved the stability of metalloporphyrin obviously.Among them,TPPMnCl supported on silica gel by coordination was highly active. |
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| Keywords: | Support Coordination Metalloporphyrins Catalytic oxidation |
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