Hydrothermal syntheses and characterization of cobalt(II) and nickel(II) complexes of 1,3-adamantanedicarboxylic acid and 1,10-phenanthroline |
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| Authors: | Hong-Zhen Xie Shi-Jie Huang Jin Zhou Shu-Ping Yu Dan-Yi Wei |
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| Institution: | (1) Faculty of Materials Science and Chemical Engineering, State Key Laboratory Base of Novel Functional Materials and Preparation Science, Ningbo University, Ningbo, Zhejiang, 315211, People’s Republic of China; |
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| Abstract: | Two coordination complexes, namely Co(phen)(H2O)L]·H2O and Ni2(phen)2(H2O)2L2]·4H2O (phen = 1,10-phenanthroline, H2L = 1,3-adamantanedicarboxylic acid) have been hydrothermally synthesized and structurally characterized by single crystal
X-ray diffraction. Co(phen)(H2O)L]·H2O consists of 1D chains of the complex plus lattice H2O molecules. Interchain hydrogen bonds and π–π stacking interactions assemble the 1D chains into 2D layers. Ni2(phen)2(H2O)2L2]·4H2O is a binuclear complex which is assembled into a 3D supramolecular structure by strong hydrogen bonds and π–π stacking interactions.
Both complexes were characterized by physico-chemical and spectroscopic methods. |
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