Corrosion inhibitive properties and electrochemical adsorption behaviour of some piperidine derivatives on brass in natural sea water |
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Authors: | Joseph Raj Xavier Rajendran Nallaiyan |
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Institution: | (1) Department of Chemistry, Anna University, Chennai, 600 025, India; |
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Abstract: | The piperidine derivatives, namely (4-Hydrazono-2,6-diphenyl-piperidin-1-yl)-ethanoic acid hydrazide; 5-(2,6-diphenyl-4-hydrazono-piperidin-1-ylmethyl)-3H-1,
3, 4]oxadiazole-2-thione; 4-amino-5-(2,6-diphenyl-4-hydrazono-piperidin-1-ylmethyl)-4H-1, 2, 4]triazole-3-thiol were synthesised
and characterised by Fourier transform-infrared spectroscopic studies to confirm the purity of compounds. The corrosion inhibition
effect of these compounds on brass in natural sea water was studied using potentiodynamic polarisation studies and electrochemical
impedance spectroscopic measurements. The presence of these inhibitors in sea water suppresses both anodic and cathodic processes,
and it is enhanced by the increase in the concentration of the inhibitors. The surface morphology of the brass after its exposure
to natural sea water with and without inhibitors was examined by scanning electron microscopy. Inductively Coupled Plasma
Atomic Emission Spectroscopic analysis were carried out after the polarisation studies showed minimum leached out of metal
ions from the brass specimen in the presence of inhibitors. The structural and electronic parameters of these piperidine derivatives
were calculated using computational methodologies. |
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