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Molecular-level investigation on electrochemical interfaces by Raman spectroscopy
Authors:TIAN  Zhong-Qun REN  BinState Key Laboratory for Physical Chemistry of Solid Surfaces
Affiliation:TIAN,Zhong-Qun REN,BinState Key Laboratory for Physical Chemistry of Solid Surfaces,Department of Chemistry,Institute of Physical Chemistry,Xiamen University,Xiamen,Fujian 361005,China
Abstract:The structure and dynamics of electrode/liquid interfaces play an increasingly important role in electrochemistry. Raman spectroscopy is capable of providing detailed structural information at molecular level and new insight into the interfacial structure, adsorption, reaction, electrocatalysis and corro-sion. In this account we will summarize some progresses of surface Raman spectroscopy in the study of electrochemical interfaces, mainly based on our group's work, laying emphasis on the detection sensitivity, spectral resolution, time resolution and spatial resolution as well as the hyphenated technique.
Keywords:Raman spectroscopy   surface enhanced Raman spectroscopy   electrochemical interfaces   adsorption
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