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Conversion of CuS thin films to structured nanosheet CuyS (1 < y ≦ 2) by vacuum annealing
Authors:J. B. Shi  P. F. Wu  Y. C. Chen  Y. C. Chang  M. Z. Tsai  F. C. Cheng  C. T. Kao  H. W. Lee  M. Y. Chen  Y. J. Huang  R. Y. Huang  S. K. Lin
Abstract:
In this study, large‐area and uniform thickness novel nano‐sheet structured CuS thin films on ITO glass have been prepared by the one‐step electrodeposition method from a dimethyl sulfoxide solution. Thin films of completely preserved nano‐sheet like morphology of CuyS (y = 1.75, 1.8, 1.95, and 2.0) are grown by vacuum annealing CuS thin films at 500 °C for different lengths of time. The 500 °C sample heated for 10 hours was nearly converted to single phase of Cu2S with y ∼ 2. The optical direct band gaps of nano‐sheet CuyS thin films annealed at 500 °C of 2, 6, and 10 hours in vacuum were found to be 1.94, 1.68, and 1.44 eV, respectively.
Keywords:Nanosheet thin films  CuyS  Electrodeposition  Optical properties
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