A homochiral diamond framework constructed from Fe(III) and Mn(II) oxo-clusters supported by Sb(III) tartrate scaffolds |
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| Authors: | Gao Qiang Wang Xiqu Jacobson Allan J |
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| Affiliation: | Department of Chemistry, University of Houston, Houston, Texas 77204-5003, USA. |
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| Abstract: | A homochiral diamond framework was obtained by using a secondary building unit (SBU) comprising an oxo-cluster containing 4Fe(III) and 3Mn(II) ions supported by Sb(3)O tartrate scaffolds. A fully protonated tetratopic cation, tetrakis(4-pyridyloxymethylene)methane (TPOM), acts as a template to arrange the clusters on a diamond lattice. |
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