Structure of excited-state transitions of individual semiconductor nanocrystals probed by photoluminescence excitation spectroscopy |
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Authors: | Htoon Han Cox Paris J Klimov Victor I |
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Institution: | Chemistry Division, Los Alamos National Laboratory, Los Alamos, New Mexico 87545, USA. |
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Abstract: | We perform for the first time photoluminescence excitation (PLE) studies of individual nanocrystals (NCs) that reveal the structure of excited-state transitions not obscured by ensemble averaging. Single-NC PLE spectra strongly deviate from a traditional idealized picture of sharp, quasiatomic resonances. We detect only a few relatively narrow transitions (3-4 meV) at the band edge, while at higher spectral energies, we observe a broad structureless feature separated from the band-edge peaks by a >50 meV "minigap." These observations can be rationalized by analyzing hole intraband relaxation behavior. |
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