| Facile Selective Diels-Alder Reactions of Chiral 5, 5-Dimethyl-4,6-Mathano-2-Methoxycarbonyl-2-Cyclohexenone. Application to the Total Synthesis of Qinghaosu |
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| 作者姓名： | LIU Hsing-Jang CHEW Sew-Yeu YEH Wen-Lung |
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| 作者单位： | LIU Hsing-Jang;CHEW Sew-Yeu;YEH Wen-Lung Department of Chemistry，The University of Alberta，Edmonton，Alberta，Canada T6G 2G2 |
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| 摘 要： | Starting from (--)-β-pinene,an efficient synthesis of qinghaosu (8) in natural form hasbeen accomplished. The synthesis involves keto ester 7 as a key intermediate which is conveniently pre-pared using the Diels-Alder chemistry developed in our laboratory.
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| 关 键 词： | (-)-β-Pinene Diels-Alder reaction synthesis of qinghaosu |
Facile Selective Diels-Alder Reactions of Chiral 5, 5-Dimethyl-4, 6-Mathano-2-Methoxycarbonyl-2-Cyclohexenone. Application to the Total Synthesis of Qinghaosu |
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| LIU Hsing-Jang,CHEW Sew-Yeu,YEH Wen-Lung.Facile Selective Diels-Alder Reactions of Chiral 5, 5-Dimethyl-4,6-Mathano-2-Methoxycarbonyl-2-Cyclohexenone. Application to the Total Synthesis of Qinghaosu[J].Chinese Journal of Organic Chemistry,1993(3). |
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| Authors: | LIU Hsing-Jang CHEW Sew-Yeu YEH Wen-Lung |
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| Institution: | LIU Hsing-Jang,CHEW Sew-Yeu,YEH Wen-Lung Department of Chemistry,The University of Alberta,Edmonton,Alberta,Canada T6G 2G2 |
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