Determination of the Tolman cone angle from crystallographic parameters and a statistical analysis using the crystallographic data base |
| |
| Authors: | Thomas E. Müller D. Michael P. Mingos |
| |
| Affiliation: | (1) Chemistry Department, Imperial College of Science, Technology and Medicine, South Kensington, SW7 2AY London, UK |
| |
| Abstract: | Summary A new method of evaluating the Tolman cone angle from X-ray structural data available from the Cambridge Crystallographic Data Base has been developed and a statistical analysis of the cone angles of the phosphines PPh3, PMe2Ph, PMePh2, PMe3, PEt3 and PCy3 (Cy = cyclohexyl) in transition metal complexes has been completed. |
| |
| Keywords: | |
| 本文献已被 SpringerLink 等数据库收录！ |
|
