Rotational analysis of the 201 and 211 bands in the Ã2Σ+-X̃ 2Π spectrum of N2O+ |
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| Authors: | J.F.M. Aarts J.H. Callomon |
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| Affiliation: | Department of Chemistry, Gorlacus Laboratories, University of Leyden, P.O. Box. 9502, 2300 RA Leyden, The Netherlands;Department of Chemistry, University College London, 20 Gordon Street, London WC1H 0AJ, UK |
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| Abstract: | Analysis of new emission spectra of Ã2Σ+-X? 2Π in N2O+, including the forbidden components with Δν2 = 1, have made it possible to locate all four vibronic components of the ν″2 = 1 manifold. Principal rotational constants and spinvibronic terms are given. A previous estimate of the Renner parameter is revised to a value of ?0.179 ± 0.002. |
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