A classical analysis of quantum resonances in isotopic collinear H + H2 reactions |
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| Authors: | J. Manz E. Pollak J. Ro¨melt |
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| Affiliation: | Lehrstuhl fu¨r Theorerische Chemie, Technische Universita¨t Mu¨nchen. D-8046 Garching, Germany;Department of Chemical Physics, Weizmann Institute of Science, Rehovot 76100, Israel;Lehrstuhl fu¨r Theoretische Chemie, Universita¨t Bonn, D-5300 Bonn 1, Germany |
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| Abstract: | ![]()
Isotopic substitution of hydrogen by muonium in the collinear H + H2 reaction causes dramatic changes in the resonance patterns of the quantum reaction probabilities. These changes are explained by a classical model. Using the systems' resonant orbits, we show that resonances appear close to energetic thresholds of new vibrational channels. |
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