Rotational and vibrational temperatures of naphthalene in a naphthalene-argon supersonic jet |
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| Authors: | JMichael Hollas Trevor Ridley Philip A Freedman |
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| Institution: | Department of Chemistry, University of Reading, Reading RG6 2AD, Berkshire, UK;Edward Davies Chemical Laboratory, University College of Wales, Aberystwyth SY23 INE, Dyfred, UK |
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| Abstract: | In the 1B2u-1Ag system of naphthalene in a supersonic jet, rotational contour calculations show rotational temperatures of 2–60 K for argon carrier gas pressures of 1520-120 Torr. The b1u vibration v24 shows a high vibrational temperature which corresponds to the seeding temperature for pressures <400 Torr. |
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