Raman and luminescence studies of alkali borate tungstate glasses

Raman and luminescence spectroscopy were used to determine the structure of alkali borate tungstate glasses: M₂O(B₂O₃)₂·xWO₃, M = Li or Na (0 < x < 1). Raman scattering results showed the dominant tungstate species in these photochromic glasses to be tetrahedral WO₄⁼. At high concentrations of WO₃, WO₃·H₂O, and W₂O₇⁼ are also present. Luminescence measurements provided evidence for an octahedral WO₃ structure not identified by the Raman results. The results also revealed a possible change in the structure of the glasses similar to that observed in alkali borate glasses and associated with the “borate anomaly”. In addition, preliminary measurements are reported on the variation of the band gap, density, index of refraction, and the elastic coefficient C₁₁ determined by Brillouin scattering with composition.