Synthesis and structural characterization of an 11-vertex nido-diphosphaborane, 7,9-Ph2-nido-7,9-P2B9H9 |
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| Authors: | Daewon Hong Patrick J Carroll Larry G Sneddon |
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| Institution: | Department of Chemistry, University of Pennsylvania, 231 South 34th Street, Philadelphia, PA 19104-6323, USA |
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| Abstract: | The new 11-vertex nido-diphosphaborane, 7,9-Ph2-nido-7,9-P2B9H9, has been synthesized by the reaction of Me4N+nido-B9H12?] with PhPCl2 in the presence of NaH. A single crystal X-ray diffraction determination and DFT/GIAO/NMR methods have both established that the compound has an open cage structure containing the phosphorus atoms in non-adjacent positions on the open face. |
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| Keywords: | Diphosphaborane Heteroborane DFT/GIAO Boron |
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