Homolytic aromatic acetylation. A new substitution reaction of arenediazonium salts |
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| Authors: | Attilio Citterio Marco Serravalle Elena Vismara |
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| Affiliation: | Istituto di Chimica del Politecnico, Piazza L. da Vinci 32, 20133 Milano Italy |
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| Abstract: | ![]()
The homolytic decomposition of arenediazonim salts induced by thermal, photochemical or redox (iron(II) salts or copper) sources in the presence of biacetyl gives substituted acetophenones with complete positional selectivity by a free-radical chain or a redox process. |
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