One-pot palladium-catalyzed synthesis of 2,3-disubstituted bicyclo[2.2.1]heptanes and bicyclo[2.2.1]hept-5-enes |
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| Authors: | Marta Catellani Gian Paolo Chiusoli |
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| Affiliation: | Istituto di Chimica Organica dell''Università, Via M. D''Azeglio 85, 43100 Parma Italy |
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| Abstract: | ![]()
A new and highly stereoselective palladium-catalyzed synthesis is reported, based on two subsequent insertions of the bicyclo[2.2.1]heptene system into an aryl or vinylpalladium bond, formed in situ from aryl or vinyl bromides. |
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