A novel aminomethylation of silyl enol ethers with aminomethyl ethers catalyzed by iodotrimethylsilane or trimethylsilyl trifluoromethanesulfonate |
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| Authors: | Akira Hosomi Susumu Iijima Hideki Sakurai |
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| Affiliation: | Department of Chemistry, Tohoku University, Sendai 980, Japan |
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| Abstract: | The iodotrimethylsilane-catalyzed reaction of silyl enol ethers with aminomethyl ethers in acetonitrile gives aminomethylation products of the corresponding ketones readily. The reaction can slso be catalyzed by trimethylsilyl trifluoromethanesulfonate in dichloromethane. |
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