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Superoxide-mediated dehydrohalogenation reactions of the pyrethroid permethrin and other chlorinated pesticides
Authors:Prem Dureja  John E. Casida  Luis O. Ruzo
Affiliation:Pesticide Chemistry and Toxicology Laboratory, Department of Entomological Sciences University of California, Berkeley, California 94720, U.S.A.
Abstract:
Superoxide generated in DMF readily converts the dihalovinyl group of permethrin and related compounds to a haloethynyl moiety and yields major products from elimination reactions of DDT, cis-chlordane, and 1,2-dibromo-3-chloropropane (DBCP).
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