On the [2,3]-sigmatropic rearrangements of sulfenate esters derived from alkenynols: synthesis of vinylallene and vinylacetylene sulfoxides. |
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Authors: | Eugène M.G.A. van Kruchten William H. Okamura |
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Affiliation: | Department of Chemistry, University of California, Riverside, California 92521 USA |
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Abstract: | The reactions of various alkenynols with phenylsulfenyl chloride result in the formation of either vinylallene sulfoxides or vnylacetylene sulfoxides, depending on the substitution pattern of the starting material. |
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