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Synthese und Struktur von Silber(II)-tetrafluoroaurat(III) Ag[AuF4]2
Authors:R. Fischer,B. G. Mü  ller
Abstract:
Synthesis and Structure of Silver(II) Tetrafluoroaurate(III) Ag[AuF4]2 Intensive green single crystals of Ag[AuF4]2 can be obtained by heating up micro crystalline Ag[AuF4]2 in autoclaves (p(F2) ~ 200 bar, T ~ 400°C, t ~ 14 d). It crystallizes monoclinic, space group P21/n ? Curn:x-wiley:00442313:media:ZAAC19976231110:tex2gif-stack-2; (No. 14) with a = 522.3(1), b = 1101.3(3), c = 550.5(2) pm, β = 94.98(3), Z = 2 and is isotypic with Pd[AuF4]2.
Keywords:Tetrafluoroaurate(III)  AgII-compounds  single crystal investigation  structure determination
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