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Polyol-Metall-Komplexe. 27. Bis-diolato-antimonate(III) mit Guanosin als Diol |
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| Authors: | Peter Klüfers Peter Mayer |
| Abstract: | Polyol Metal Complexes. 27. Bis-Diolato Antimonates(III ) with Guanosine as the Diol The complex anions of K3SbIII(Guo1,2′,3′H?3)2] · 10 H2O ( 1 ) and Co(NH3)6]SbIII(Guo1,2′,3′H?3)2] · 9 H2O ( 2 ) are four-coordinate homoleptic bis(diolato)antimonate(III ) species. The guanosine trianions act as carbohydrate ligands through their cis-furanoidic ribosyl moiety, thus forming no nucleobase–metal bonds. |
| Keywords: | Guanosine Ribofuranoside Ligands Antimonate(III) Crystal Structures |