Cobalt(II), Nickel(II), and Copper(II) Complexes with Diphenylthiocarbazide |
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Authors: | Koksharova T. V. Fel'dman S. V. |
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Affiliation: | (1) Mechnikov University, ul. Petra Velikogo 2, Odessa, 270100, Ukraine |
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Abstract: | New [ML(H2O)2] complexes (M = Co2+, Ni2+, or Cu2+; H2L = diphenylthiocarbazide) were synthesized and studied using IR and diffuse reflection electronic spectroscopy, magnetic chemistry, conductometry, and DTA. The metals were shown to coordinate L2–through nitrogen and sulfur atoms. The complex [CuL(H2O)2] is a dimer. |
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