| 两亲性卟啉的合成及其L—B膜 |
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| 引用本文： | 文珂,曹锡章.两亲性卟啉的合成及其L—B膜[J].应用化学,1992,9(3):70-71. |
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| 作者姓名： | 文珂 曹锡章 |
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| 作者单位： | 吉林大学化学系，吉林大学化学系 长春 130023，长春 130023 |
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| 摘 要： | 早期L-B膜的研制主要着眼于长碳链脂肪酸及其衍生物。近来,由于对膜性能的特殊要求,人们把注意力转向丁二炔、酞菁和卟啉衍生物。本文用四一(N,N-二甲基氨基苯基)卟啉(TDMAPP)与溴代十六烷反应得到两亲性的含有4个长碳链的澳化四-(4-
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| 关 键 词： | 卟啉衍生物 合成 L－B膜 |
| 收稿时间： | 1991-05-05 |
SYNTHESES OF AMPHIPHILIC PORPHYRINS AND THEIR LANGMUIR-BLODGETT FILMS |
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| Wen Ke,Cao Xizhang.SYNTHESES OF AMPHIPHILIC PORPHYRINS AND THEIR LANGMUIR-BLODGETT FILMS[J].Chinese Journal of Applied Chemistry,1992,9(3):70-71. |
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| Authors: | Wen Ke Cao Xizhang |
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| Abstract: | Tetra-(N,N-dimethylaminophenyl)porphyrin(TDMAPP) reacts with n-C_(16)H_(33)Br to give quaternary bromides of the amphiphilie porphyrin containing four long aliphatic chains. Its Cu, Zn and Co complexes have been prepared. These porphyrins are capable of forming Langmuir-Blodgett films. The UV-Visible spectra of the L-B films as well as of the solid compounds indicate that the interations between molecules in two cases are different. |
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| Keywords: | long chain porphyrin derivative synthesis L-B film |
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