A novel parallel interpenetrating two‐dimensional (4,4) network: poly[[μ2‐1,4‐bis(imidazol‐1‐ylmethyl)benzene](μ2‐naphthalene‐1,4‐dicarboxylato)zinc(II)] |
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Authors: | Ya‐Ping Li Da‐Jun Sun Hu Zang Guan‐Fang Su Yu‐Lin Li |
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Abstract: | In the title coordination compound, Zn(C12H6O4)(C14H14N4)]n, the two ZnII centers exhibit different coordination environments. One ZnII center is four‐coordinated in a distorted tetrahedral environment surrounded by two carboxylate O atoms from two different naphthalene‐1,4‐dicarboxylate (1,4‐ndc) anions and two N atoms from two distinct 1,4‐bis(imidazol‐1‐ylmethyl)benzene (1,4‐bix) ligands. The coordination of the second ZnII center comprises two N atoms from two different 1,4‐bix ligands and three carboxylate O atoms from two different 1,4‐ndc ligands in a highly distorted square‐pyramidal environment. The 1,4‐bix ligand and the 1,4‐ndc anion link adjacent ZnII centers into a two‐dimensional four‐connected (4,4) network. The two (4,4) networks are interpenetrated in a parallel mode. |
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