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Mechanically fabricated Metal–organic framework/resin composite nanoparticles for efficient basic catalysis
Authors:Zhi‐Hui Zhang  Bing‐Bing Qian  Pan‐Pan Sheng  Sen Yang  Xian‐Feng Huang  Jin‐Long Wang  Qun Chen  Liang Wang  Ming‐Yang He
Abstract:Zeolitic imidazolate framework‐8 (ZIF‐8) was successfully composited with an anionic basic resin 201 × 7 (717‐resin) to provide a novel ZIF‐8/717‐resin composite. Its catalytic activity toward the Knoevenagel condensation reaction was evaluated. Results showed that ZIF‐8/717‐resin composite could efficiently catalyze this reaction, affording the corresponding products in good to excellent yields. Good functional group tolerance, mild reaction conditions, good stability and reusability of the catalyst are the major features of present protocol.
Keywords:composite  Knoevenagel condensation  mechanical fabrication  metal–  organic   frameworks  synergistic catalysis
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