| 3-叠氮基-4-酰氯肟基呋咱的合成及其热稳定性 |
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| 引用本文： | 周彦水,霍欢,周诚,王伯周,陈智群,张叶高,王锡杰.3-叠氮基-4-酰氯肟基呋咱的合成及其热稳定性[J].合成化学,2011,19(5):665-666,687. |
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| 作者姓名： | 周彦水 霍欢 周诚 王伯周 陈智群 张叶高 王锡杰 |
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| 作者单位： | 西安近代化学研究所,陕西西安,710065 |
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| 基金项目： | 国家基础科研基金资助项目(2371000415) |
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| 摘 要： | 以3-氨基-4-酰氨肟基呋咱为原料,经重氮化和叠氮化反应合成了新化合物3-叠氮基-4-酰氯肟基呋咱(3),总收率67％.其结构经1H NMR,13C NMR,15N NMR,IR及元素分析表征.热失重法研究结果表明,3具有良好的热稳定性.
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| 关 键 词： | 3-叠氮基-4-酰氯肟基呋咱 合成 热稳定性 |
Synthesis and Thermal Stability of 3-Azido-4-carboxchloridoximefurazan |
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| ZHOU Yan-shui,HUO Huan,ZHOU Cheng,WANG Bo-zhou,CHEN Zhi-qun,ZHANG Ye-gao,WANG Xi-jie.Synthesis and Thermal Stability of 3-Azido-4-carboxchloridoximefurazan[J].Chinese Journal of Synthetic Chemistry,2011,19(5):665-666,687. |
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| Authors: | ZHOU Yan-shui HUO Huan ZHOU Cheng WANG Bo-zhou CHEN Zhi-qun ZHANG Ye-gao WANG Xi-jie |
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| Institution: | ZHOU Yan-shui,HUO Huan,ZHOU Cheng,WANG Bo-zhou,CHEN Zhi-qun,ZHANG Ye-gao,WANG Xi-jie(Xi'an Modern Chemistry Research Institute,Xi'an 710065,China) |
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| Abstract: | A novel compound,3-azido-4-carboxchloridoximefurazan(3),in overall yield of 67% was synthesized by diazotization and azidation from 3-amino-4-amidoximinofurazan.The structure was characterized by 1H NMR,13C NMR,15N NMR,IR,MS and elemental analysis.The results showed that 3 exhibited good thermal stability by DSC. |
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| Keywords: | 3-azido-4-carboxchloridoximefurazan synthesis thermal stability |
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