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Effect of collision-induced phase-shifts on the line widths and line shifts of CO2-Ar system
Authors:M L Kurtadikar  S C Mehrotra
Institution:(1) Department of Physics, Marathwada University, University Campus, 431 004 Aurangabad, India;(2) Government Polytechnic, Station Road, 431 005 Aurangabad, India;(3) Department of Chemical Physics, University of Kiel, Kiel, West Germany
Abstract:The theoretical calculation of line widths and line shifts for CO2-Ar system is computed by the Mehrotra-Boggs theory. It is shown for this system that the phase shift effect is very important at large values of |m| wherem is the value of rotational quantum numberJ in the lower vibrational state. It is also pointed out that the Salesky-Korff theory is the same as the Mehrotra-Boggs theory.
Keywords:Collision-induced line shape  phase shift effect  CO2-Ar system  Mehrotra-Boggs theory
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