| Structure of Molybdenum Complex of Benzothiazole－2－thiolate（η~5－C_5H_5）Mo（CO）_2（C_7H_4NS_2） |
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| 引用本文： | Cheng Guo-Bao,Wu Qiang-Jin,Huang Xiao-Ying￣b.Structure of Molybdenum Complex of Benzothiazole－2－thiolate（η~5－C_5H_5）Mo（CO）_2（C_7H_4NS_2）[J].结构化学,1995(1). |
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| 作者姓名： | Cheng Guo-Bao Wu Qiang-Jin Huang Xiao-Ying￣b |
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| 作者单位： | Cheng Guo-Bao;Wu Qiang-Jin;Huang Xiao-Ying￣b(State Key Laboratory of Structural Chemistry，Fuzhou，China)(Dalian Institute of Chemical Physics，Dalian，116023)(Fujian Institute of Research on the Structure of Matter，Fuzhou，350002) |
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| 摘 要： | ＳｔｒｕｃｔｕｒｅｏｆＭｏｌｙｂｄｅｎｕｍＣｏｍｐｌｅｘｏｆＢｅｎｚｏｔｈｉａｚｏｌｅ－２－ｔｈｉｏｌａｔｅ（η~５－Ｃ_５Ｈ_５）Ｍｏ（ＣＯ）_２（Ｃ_７Ｈ_４ＮＳ_２）ＣｈｅｎｇＧｕｏ－Ｂａｏ~ａ；ＷｕＱｉａｎｇ－Ｊｉｎ~ｂ；ＨｕａｎｇＸｉａｏ－Ｙｉｎｇ~...
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Structure of Molybdenum Complex of Benzothiazole-2-thiolate(η￣5-C_5H_5)Mo(CO)_2(C_7H_4NS_2) |
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| Abstract: | C_(14)H_9NO_2S_2Mo,Mr=383.29,triclinic,space group P1,a=11.658(4),b=16.218(8),c=7.895(3),a=97.58(4),β=106.04(3),γ=85.62(3)°,V=1421(2),Z=4,D_c=1.79 g/cm￣3,μ=11.81 cm￣(-1).F(000)=760.Refinement converged to R=0.049 and Rω=0.058 for 3153 independent observed reflections.The compound is a mononuclear molybdenum complex containing benzothiazole-2-thiolato ligand.The molybdenum atom is coordinated by the two carbonyl carbon atoms,tlie cyclopentadienyl carbon atoms,and the nitrogen atom and sulfur atom of benzothiazole-2-thiolate.The coordination polyhedron may be described as a trapezoidal pyramid with the Cp ring centroid as a top. |
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| Keywords: | crystal structure molybdenum complex benzothiazole-2-thiolate |
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