Fluoroaliphatic esters of fluorosulfonic acid. 4. Reactions of α-fluorosulfatoperfluoro ketones with nucleophilic reagents |
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Authors: | V. M. Rogovik N. I. Delyagina E. I. Mysov V. F. Cherstkov S. R. Sterlin L. S. German |
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Affiliation: | (1) A. N. Nesmeyanov Institute of Organometallic Compounds, Academy of Sciences of the USSR, Moscow |
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Abstract: | -Fluorosulfatoperfluoroethyl isopropyl ketone I and fluorosulfatopentafluoroacetone II react with alkali metal chlorides and bromides to form the corresponding -haloperfluoro ketones as a result of direct nucleophilic substitution.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 2066–2069, September, 1990. |
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