Photoelectron spectra of polyunsaturated [4,4,2]propellanes |
| |
| Authors: | R. Gleiter E. Heilbronner L.A. Paquette G.L. Thompson R.E. Wingard |
| |
| Affiliation: | Physikalisch-Chemisches Institut der Universität Basel, Switzerland;Department of Chemistry, The Ohio State University, Columbus, Ohio U.S.A. |
| |
| Abstract: | The photoelectron spectra of the six propellanes 1 to 6 have been recorded. Those bands which correspond to ejection of an electron from a π-orbital have been assigned, using the concept of through bond and through space interaction. Homoconjugative interaction between the π-systems of the two butadiene moieties of 6 is of the same order as that of the π-orbitals in norbornadiene. |
| |
| Keywords: | |
| 本文献已被 ScienceDirect 等数据库收录！ |
|
