Abstract: | We have developed efficient organic electroluminescent (EL) devices using a phosphorescent material, tris(2‐phenylpyridine) iridium, Ir(ppy)3, as an emitter material and a polymer buffer layer, tetraphenyldiamine‐containing poly(arylene ether sulfone) (PTPDES) doped with tris(4‐bromophenyl) aminium hexachloroantimonate (TBPAH) as an electron acceptor. In this device, a high external quantum efficiency of 21.6% and a luminous efficiency of 82 lm/W (77 cd/A) at 3.0 V were obtained. These high efficiencies can be explained by high quantum efficiency due to phosphorescent Ir(ppy)3 and high luminous efficiency realized by the use of the polymer buffer layer. Copyright © 2002 John Wiley & Sons, Ltd. |