Gold‐Catalyzed 1,2‐Oxoarylations of Nitriles with Pyridine‐Derived Oxides |
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| Authors: | Somnath Narayan Karad Prof. Dr. Rai‐Shung Liu |
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| Affiliation: | Department of Chemistry, National Tsing‐Hua University, Hsinchu (30013) (Taiwan) |
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| Abstract: | We report the first success in the gold‐catalyzed oxoarylations of nitriles with pyridine‐derived N‐oxides using gold carbenes as initiators. These oxoarylations were also achieved satisfactorily in intermolecular three‐component oxidations, including diverse alkenyldiazo esters, nitriles, and pyridine‐based oxides. |
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| Keywords: | carbenes gold heterocycles nitrogen oxides synthetic methods |
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