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Eu3+掺杂钛酸钇晶态薄膜的制备与高效红色荧光发射
引用本文:李晓娟,陈宝玖,林海.Eu3+掺杂钛酸钇晶态薄膜的制备与高效红色荧光发射[J].发光学报,2008,29(1):89-92.
作者姓名:李晓娟  陈宝玖  林海
作者单位:1. 大连工业大学化工与材料学院, 辽宁, 大连, 116034;2. 大连海事大学物理系, 辽宁, 大连, 116026
基金项目:辽宁省大连市科技计划 , 教育部留学回国人员科研启动基金
摘    要:采用溶胶-凝胶法制备了Eu3+掺杂的钛酸钇晶态发光薄膜。通过X射线衍射(XRD)对薄膜的结构和结晶过程进行了分析,利用荧光分光光度计对薄膜的发光性质开展了测试和研究。XRD结果表明,薄膜包含立方相YxTi1-xO1-0.5x晶粒,该晶粒属立方晶系,Fm3m(225)空间群,晶胞参数a=0.530nm,晶粒尺寸约为17nm。荧光光谱表明,Eu3+掺杂的YxTi1-xO1-0.5x薄膜显示了强的红光发射,其中Eu3+5D07F2超灵敏跃迁为最强一组。紫外氙灯、准分子激光器、汞灯等是这种发光薄膜的有效激发源。

关 键 词:  钛酸钇  晶态薄膜  红光发射
文章编号:1000-7032(2008)01-0089-04
收稿时间:2007-08-25
修稿时间:2007-11-04

Deposition and Effective Red Emission of Eu3+-doped YxTi1-xO1-0.5x Crystal Phosphor Film
LI Xiao-juan,CHEN Bao-jiu,LIN Hai.Deposition and Effective Red Emission of Eu3+-doped YxTi1-xO1-0.5x Crystal Phosphor Film[J].Chinese Journal of Luminescence,2008,29(1):89-92.
Authors:LI Xiao-juan  CHEN Bao-jiu  LIN Hai
Institution:1. Faculty of Chemical Engineering and Materials, Dalian Polytechnic University, Dalian 116034, China;2. Department of Physics, Dalian Maritime University, Dalian 116026, China
Abstract:Eu3+-doped YxTi1-xO1-0.5x crystal film was spin-coated on quartz glass substrates through sol-gel route. The structure and luminescence properties of the resultant film were investigated by X-ray diffraction (XRD) and fluorescence spectrometer, respectively. The results of XRD revealed that the film was made up of YxTi1-xO1-0.5x grains with cubic structure in average size about 17 nm. Typical Eu3+ emission peaks were observed and the strongest emission with red color corresponds to the 5D07F2 transition. UV xenon lamps, excimer lasers and mercury lamp are powerful excitation sources for Eu3+ visible fluorescence in the Eu3+-doped YxTi1-xO1-0.5x crystal film.
Keywords:europium  yttrium titanate  crystal film  red emission
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