Synthesis of new colloidal formations during the strengthening of different activated hydrated metallurgical slags |
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Authors: | Vsvolod A Mymrin Haroldo A Ponte Carlos I Yamamoto |
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Institution: | a Russian Academy of Natural Sciences, Moscow, Russia b Chemical Engineering Department, Centro Politécnico, Federal University of Paraná, CEP 81531-990, Curitiba, Brazil |
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Abstract: | This paper reports on a comparison of experimental researches on the hydration hardening of different types of dumped ferrous slag (DFS) (blast furnace, open hearth, electric steel and converter), non-activated and activated with small (2%) additions of Portland cement or lime. Activation was found to accelerate the strengthening processes in the early stages of hydration resulting from the growth of colloidal sol–gel new formations in a more alkaline environment. Over time, these formations became denser and transformed into stone-like amorphous materials with a uniaxial strength of up to 47.6 MPa at 1 year of age. All these types of slag can, therefore, be used in different applications, for example, like traditional binders, such as Portland cement, to different ceramic goods, new construction materials, etc. But till now the results of this research were used only for the preparing of binder materials for natural soils strengthening as road bases in Russia. Highways whose roadbeds were built with these DFS as binder materials have shown excellent performance indices in different parts of Russia, including Siberia and northern regions. |
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Keywords: | Dump ferrous slags Chemical interaction Sol–gel Colloidal new formations Syneresis of gel |
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