Synthesis of all diastereomeric methyl 2,5-anhydro-3-deoxy-hexonates: precursors to C-2-deoxynucleosides and THF-templated γ- and δ-amino acids |
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| Authors: | Mark P WattersonAlison A Edwards John A LeachMartin D Smith Osamu IchiharaGeorge WJ Fleet |
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| Institution: | a Dyson Perrins Laboratory, South Parks Road, University of Oxford, Oxford OX1 3QY, UK
b Evotec OAI, 151 Milton Park, Abingdon, Oxfordshire OX14 4SD, UK |
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| Abstract: | Efficient syntheses of all diastereomers of methyl 2,5-anhydro-3-deoxy-hexonate from mannono- or gulono-lactones provide precursors for C-nucleosides of 2-deoxyribose and for THF-templated γ- and δ-amino acids. |
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