One-step conversions of a simple corrole into chiral and amphiphilic derivatives |
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| Authors: | Irena SaltsmanIsrael Goldberg Zeev Gross |
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| Institution: | a Department of Chemistry and Institute of Catalysis Science and Technology, Technion-Israel Institute of Technology, Haifa 32000, Israel
b School of Chemistry, Sackler Faculty of Exact Sciences, Tel Aviv University, Tel Aviv 69978, Israel |
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| Abstract: | The reactions of phosgene with 5,10,15-tris(pentafluorophenyl)corrole and its gallium(III) complex lead to a novel chiral macrocycle and an amphiphilic corrole, respectively. Both types of molecules were fully characterized by spectroscopy and X-ray crystallography. |
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