The sulfinyl moiety as an internal nucleophile. Part 8: Efficient, stereospecific synthesis of (+)-polyoxamic acid |
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| Authors: | Sadagopan Raghavan Suju C. Joseph |
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| Affiliation: | Organic Division I, Indian Institute of Chemical Technology, Hyderabad 500 007, India |
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| Abstract: | ![]()
A straightforward and stereospecific synthesis of (+)-polyoxamic acid is disclosed. The key step of the synthesis involves the regio- and stereospecific bromohydration of an olefin via intramolecular participation by the sulfinyl group. |
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| Keywords: | (+)-polyoxamic acid sulfinyl group bromohydrin stereospecific |
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